(Ph3P)2Rh(SPCy2): A complex containing a side-on bonded η2-secondary phosphine sulfide anion

Adsorption of Phosphine on a BN Nanosurface

Electrical sensitivity of a Boron Nitride Nano Sheet (BNNS) to phosphine (PH3) molecule is studied using Density Functional Theory (DFT) calculations at the B3LYP/6-31G(d) level of theory. The adsorption energy (Ead) of phosphine on the surface of the pristine Nanosheet is about -678.96×1019eV. Pristine BNNS is a suitable adsorbent for phosphine and can be u...

Triply-Bonded OszBrs2- Anion

Treatment of H20sBr6 with 1.5 equiv of CsMe5H in a mixture of 48% HBr and methanol or ethanol at reflux for 3 h gives a brown precipitate which has the empirical formula " ( C ~ M ~ ~ ) Z O S ~ B ~ ~ H " ; actually, this product is the unusual salt [ ( C ~ M ~ ~ ) ~ O S H ] ~ [ O S ~ B ~ ~ ] where the cation is the conjugate acid of decamethylosmocene and the anion contains an Os-Os triple bond...

Approach to Chronic Secondary Headache: A Case report on Unusual Drug Side Effects

In this article, we present the case of a 12-year-old female child who complained of bilateral temporal and frontal headache for 2 to 3 months with nausea and vomiting. Physical examination revealed right-sided sixth cranial nerve palsy and papilledema in ophthalmoscopy. To find the cause of increased intracranial pressure, the patient underwent brain imaging and brain MRI showed no abnormality...

Self-assembly of a hydrogen bonded framework from a gold phosphine complex with a pendant uracil group.

The easily prepared complex AuCl(PPh(2)Ur) (Ur = uracil) self-assembles in the solid state to form crystals containing solvent-accessible channels, the structure remains crystalline even after removal and re-addition of solvent.

Synthesis and Characterization of New Phosphine oxide and Ketone Containing Poly(Arylene Sulfide Sulfone)s